Cp2TiCl2-catalyzed hydromagnation of disubstituted acetylenes as a stereo-specific route to Z-alkenes

Autor:	O. S. Vostrikova, R. M. Sultanov, Usein M. Dzhemilev, A. R. Gimaeva
Rok vydání:	1988
Předmět:	Catalytic complex Chemistry Reagent Organic chemistry Nanotechnology General Chemistry Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:1936-1939
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00962519
Popis:	The hydromagnation reaction of disubstituted acetylenes has been systematically studied in the presence of catalytic quantities of Cpcc 2TiCl2. It was found that the conditions used to form the catalytic complex exerted the decisive effect on the course of the reaction, and that the most active hydromagnation reagents were n-Pr2Mg and i-Bu2Mg. The hydrotitanation of disubstituted acetylenes using Cp2TiH was also demonstrated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6004dfe6ea30c4d3c3144b5057e72035 https://doi.org/10.1007/bf00962519 Zobrazit plný text záznamu Full text from SpringerLink