Synthesis of ortho-substituted benzophenones by way of benzophenones carrying A t-butyl group as a blocking group

Autor:	D. J. Reiding, W. Th. Nauta, Petrus Simon Hofman
Rok vydání:	2010
Předmět:	Ortho position chemistry.chemical_compound Group (periodic table) Chemistry Stereochemistry Yield (chemistry) General Chemistry Blocking (statistics) Medicinal chemistry Toluene
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 79:790-793
ISSN:	0165-0513
DOI:	10.1002/recl.19600790804
Popis:	Whereas benzoylation of toluene or m-xylene is known to lead to a mixture of 2- and 4-methylbenzophenone and to 2,4-dimethylbenzophenone respectively, the presence of a blocking t.butyl group in the 4- and the 5-positions respectively leads to products which on debutylation yield benzophenones with substituents in the ortho position only.
Databáze:	OpenAIRE
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