Synthesis and characterisation of [OC-6-33][OsCl2(CO)2L2] (L=phosphine). Crystal structure of [OC-6-33][OsCl2(CO)2(PEt3)2]

Autor:	Karl S. Coleman, Howard C.S. Clark, Jane Redding, Eric G. Hope, John H. Holloway, David R. Russell, John Fawcett
Rok vydání:	1999
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Materials Chemistry Crystal structure Physical and Theoretical Chemistry Medicinal chemistry Phosphine
Zdroj:	Polyhedron. 18:1207-1210
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(98)00417-3
Popis:	A series of [OC-6-33][OsCl2(CO)2L2] (L=phosphine) complexes have been prepared by cleavage of [OsCl(μ-Cl)(CO)3]2 with a variety of phosphines for a comparison of spectroscopic data with those for the related [OC-6-13][OsF2(CO)2L2] (L=phosphine). The X-ray structural characterisation of [OC-6-33][OsCl2(CO)2(PEt3)2] represents the first structural characterisation for this class of complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5faab6d86496fbd2aca3cfaec785b02e https://doi.org/10.1016/s0277-5387(98)00417-3 Zobrazit plný text záznamu Full Text from ScienceDirect