A matrix isolation study of the water complexes of chlorine, chlorine oxides (ClOCl, OClO) and hypochlorous acid and their photochemistry

Autor:	Bengt Nelander, Klas Johnsson, Anders Engdahl, Pernilla Ouis
Rok vydání:	1992
Předmět:	Argon Hypochlorous acid Inorganic chemistry General Engineering Matrix isolation Infrared spectroscopy chemistry.chemical_element Photochemistry Oxygen Acceptor chemistry.chemical_compound chemistry Chlorine Physical and Theoretical Chemistry Lone pair
Zdroj:	The Journal of Physical Chemistry. 96:5778-5783
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100193a023
Popis:	The IR spectra and photochemistry of the binary water complexes of Cl 2 , ClOCl, HOCl, and OClO, isolated in argon matrices, have been studied. Water acts as a lone pair done toward Cl 2 , ClOCl, and ClO 2 , probably with the water oxygen next to a chlorine atom in all three cases. Irradiation of the water-chlorine complex with near-UV radiation produces a complex between HOCl and HCl, with HCl as proton donor and HOCl as acceptor.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5fa6b5f29b2063f62ae055e42791e708 https://doi.org/10.1021/j100193a023 Zobrazit plný text záznamu