Structural and optical properties of amorphous In1−xPx films

Autor: S.H. Baker, E.A. Davis, B T Williams, S.C. Bayliss, S J Gurman, N Elgun
Rok vydání: 1994
Předmět:
Zdroj: Journal of Non-Crystalline Solids. 169:111-125
ISSN: 0022-3093
DOI: 10.1016/0022-3093(94)90230-5
Popis: In 1− x P x films have been prepared by rf sputtering with compositions in the range 0.4 x x > 0.5 but In-rich films contained crystallites. Extended X-ray absorption fine structure (EXAFS) and X-ray photoelectron spectroscopy measurements indicate that there is chemical disorder in the structural network of the a-In 1− x P x films, although chemical ordering is predominant. Optical absorption data are found to be consistent with this assertion. Partial coordination numbers, deduced from the EXAFS measurements, are interpreted using thermodynamic arguments.
Databáze: OpenAIRE