Porphyrin Derivatives of Macrocyclic Tetraindoles: Synthesis and Chemical Transformations

Autor:	K. M. Dyumaev, A. Ya. Vainer, K. I. Zelikson, N. V. Barannik, S. V. Kotov, A. M. Kovalenko
Rok vydání:	2018
Předmět:	010405 organic chemistry General Chemistry Photoresist 010402 general chemistry 01 natural sciences Porphyrin Combinatorial chemistry 0104 chemical sciences chemistry.chemical_compound Nanolithography chemistry Resist Polyphenol Tetraindole
Zdroj:	Doklady Chemistry. 480:77-80
ISSN:	1608-3113 0012-5008
Popis:	Polyphenols chemically bonded to a molecular platform based on macrocyclic tetraindole porphyrin derivatives were synthesized for the first time. The tetraindole was prepared by two-step tetramerization of 3-(4′-bromophenyl)-4,6-dimetoxyindole. Polyphenols of this type were obtained by the Suzuki–Miyaura reaction between bromo-containing cyclic tetraindole and monoboryl-substituted porphyrin. The subsequent transformations of this molecular construction gave rise to epoxidized polyphenol on a tetraindole support, which served for the development of a new negative resist for electron-beam nanolithography. The resist can form patterns with a 12 nm resolution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5f985c2cd54bc297f461134cc97b381d https://doi.org/10.1134/s0012500818050026 Zobrazit plný text záznamu Plný text ve formátu PDF