A kinetic study of mechanochemical halogen bond formation by in situ31P solid-state NMR spectroscopy
| Autor: | Lysiane Champion, David L. Bryce, Yijue Xu, Bulat Gabidullin |
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| Rok vydání: | 2017 |
| Předmět: |
Halogen bond
Chemistry Metals and Alloys 02 engineering and technology General Chemistry Activation energy 010402 general chemistry 021001 nanoscience & nanotechnology Kinetic energy Photochemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Reaction rate chemistry.chemical_compound Solid-state nuclear magnetic resonance Materials Chemistry Ceramics and Composites 0210 nano-technology Spectroscopy Spinning Triphenylphosphine oxide |
| Zdroj: | Chemical Communications. 53:9930-9933 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | In situ31P solid-state NMR studies of halogen bond formation between triphenylphosphine oxide and para-diiodotetrafluorobenzene provide insights into the cocrystallisation process and provide an estimate of the activation energy. The effects of temperature, magic-angle spinning speed, and initially added liquid on the reaction rate and mechanism have been investigated. |
| Databáze: | OpenAIRE |
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