The effect of a liquid crystal medium on the decomposition of?-nitrophenyl dimethylthiophosphate

Autor:	B. E. Ivanov, G. V. Dmitrieva, L. A. Kudryavtseva, R. F. Bakeeva, V. E. Bel'skii
Rok vydání:	1990
Předmět:	chemistry.chemical_compound chemistry Nucleophile Liquid crystal Phase (matter) Inorganic chemistry Polymer chemistry Ethylenediamine Lamellar structure General Chemistry Decomposition Ion Thiophosphate
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1048-1050
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00961712
Popis:	The lamellar liquid crystal meso phase formed in the cetyltrimethylammonium bromide-1-hexanol-water system assists the reaction of p-nitrophenyl dimethyl thiophosphate with a charged nucleophile (hexanolate anion) and uncharged nucleophile (ethylenediamine) with the loss of the p-nitrophenylmethylthiophosphate anion, i.e., the reaction at the carbon atom and not at the phosphorus atom.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5f6d70a4f16b1d7af224f5e83764b896 https://doi.org/10.1007/bf00961712 Zobrazit plný text záznamu Full text from SpringerLink