ChemInform Abstract: Trifluoroacetylation of Ketone O-Vinyloximes

Autor: D. S. D. Toryashinova, E. Yu. Shmidt, A. M. Vasil'tsov, Boris A. Trofimov, L. N. Il'icheva, Ol'ga A. Tarasova, Alexey B. Zaitsev, A. I. Mikhaleva, Andrei V. Afonin
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 32
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200141088
Popis: Ketone oxime O-vinyl ethers having alkyl or phenyl radicals react with trifluoroacetic anhydride in ether in the presence of pyridine, yielding 43-54% of the corresponding ketone oxime O-(trans-4,4,4-trifluoro-3-oxo-1-butenyl) ethers with high stereoselectivity.
Databáze: OpenAIRE