ChemInform Abstract: Trifluoroacetylation of Ketone O-Vinyloximes
Autor: | D. S. D. Toryashinova, E. Yu. Shmidt, A. M. Vasil'tsov, Boris A. Trofimov, L. N. Il'icheva, Ol'ga A. Tarasova, Alexey B. Zaitsev, A. I. Mikhaleva, Andrei V. Afonin |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 32 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.200141088 |
Popis: | Ketone oxime O-vinyl ethers having alkyl or phenyl radicals react with trifluoroacetic anhydride in ether in the presence of pyridine, yielding 43-54% of the corresponding ketone oxime O-(trans-4,4,4-trifluoro-3-oxo-1-butenyl) ethers with high stereoselectivity. |
Databáze: | OpenAIRE |
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