Isomerization of Perezone into Isoperezone and Preparation of Dihydroisoperezinone

Autor:	Benjamín Ortiz, O. Collera, William F. Reynolds, Francisco Yuste, Raúl G. Enríquez, Margaret Yu, Rubén Sánchez-Obregón, Fernando Walls, Héctor Barrios, A. Rodríguez-hernández
Rok vydání:	1994
Předmět:	Chemistry Stereochemistry Transposition (telecommunications) Molecular Medicine Ring (chemistry) Isomerization Isoperezone
Zdroj:	Natural Product Letters. 4:133-139
ISSN:	1057-5634
DOI:	10.1080/10575639408044925
Popis:	The reaction of perezone 1 with 3,4,5,6-tetrahydro-2-pyrimidinethiol 11 promotes a 1,2-carbonyl transposition in the quinoid ring of 1 giving rise to isoperezone 8, which treated with BF3·Et2O produces dihydroisoperezinone 9.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5f52e7ffbcf4a68e00292550ef46a7e2 https://doi.org/10.1080/10575639408044925 Zobrazit plný text záznamu