Autor:	Howard Alper, Bertrand Despeyroux, Frederick W. Hartstock
Rok vydání:	1984
Předmět:	chemistry.chemical_compound chemistry Allene Product (mathematics) Yield (chemistry) Alkoxy group General Medicine Medicinal chemistry
Zdroj:	Chemischer Informationsdienst. 15
ISSN:	0009-2975
DOI:	10.1002/chin.198447150
Popis:	Allene undergoes alkoxy–alkoxycarbonylation under exceedingly mild conditions (CO–O2–MeOH–PdCl2–CuCl2, 0 °C, 1 atm) affording methyl 2-methoxymethylacrylate in good yield; in the case of 1,1-disubstituted allenes the reaction is regiospecific although the product yields are lower.
Databáze:	OpenAIRE
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