Influence of different alkyl and carboxylate substituents on Sn(IV) organometallic catalysts during fatty acid methyl ester production

Autor:	Paula R. Mendes, Danielle M. de A. Fragoso, Simoni M.P. Meneghetti, Mario R. Meneghetti, Jhosianna P.V. da Silva, Ana Soraya Lima Barbosa, Janaína H. Bortoluzzi, Yariadner C. Brito
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Steric effects Process Chemistry and Technology General Chemistry Transesterification Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Organic chemistry Reactivity (chemistry) Carboxylate Methanol Fatty acid methyl ester Alkyl
Zdroj:	Catalysis Communications. 58:204-208
ISSN:	1566-7367
Popis:	Sn(IV) complexes (dimethyltin dineodecanoate (1), dibutyltin dineodecanoate (2), dioctyltin dineodecanoate (3), dimethyltin diundec-10-enoate (4), dibutyltin diundec-10-enoate (5), tributyltin undec-10-enoate (6) and tributyltin undecanoate (7)) were tested as catalysts for transesterification or esterification in the presence of methanol, in order to investigate the effect of the substituents coordinated to the metal center. All complexes were active at relative high reaction temperatures, and their reactivity can be associated with the steric effects induced by the substituents (alkyls and carboxylates) at the metal center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5f3f42e6c861663dba665608925b7b08 https://doi.org/10.1016/j.catcom.2014.09.010 Zobrazit plný text záznamu Full Text from ScienceDirect