Direct conversion of syngas into aromatics over a bifunctional catalyst: inhibiting net CO2 release

Autor:	Jincan Kang, Zhiqiang Zhang, Qinghong Zhang, Haoren Yin, Wei Zhou, Guoquan Zhang, Cheng Zhou, Ye Wang, Xiaojian Min, Kang Cheng, Xinlei Zheng, Jiaqing Shi
Rok vydání:	2020
Předmět:	Tandem Chemistry Metals and Alloys General Chemistry Combinatorial chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Bifunctional catalyst chemistry.chemical_compound Materials Chemistry Ceramics and Composites Methanol Syngas
Zdroj:	Chemical Communications. 56:5239-5242
ISSN:	1364-548X 1359-7345
Popis:	Tandem catalysis via methanol intermediate is a promising route for the direct conversion of syngas into aromatics. However, the simultaneous formation of CO2 is a serious problem. Here, we demonstrate that CO2 was formed by the water-gas shift (WGS) reaction (CO + H2O → CO2 + H2) over a ZnO–ZrO2/H-ZSM-5 catalyst, and the net CO2 formation could be inhibited without affecting the formation of aromatics by co-feeding CO2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5f04cac05f643d801ba9993f4e5d7d6a https://doi.org/10.1039/d0cc00608d Zobrazit plný text záznamu