ChemInform Abstract: Synthesis of Carbamates from Diethoxycarbonyl Hydrazine Derivatives by E1cB Eliminative Cleavage of the N-N′-Bond Rather than Reduction

Autor:	Philip Magnus, Negar Garizi, Alexandra Ornholt, Kimberly A. Seibert
Rok vydání:	2010
Předmět:	Chemistry General Medicine Cleavage (embryo) Medicinal chemistry Hydrazine derivatives Bond cleavage E1cB-elimination reaction
Zdroj:	ChemInform. 41
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.201019052
Popis:	Treatment of diethoxycarbonyl hydrazine derivatives with methyl bromoacetate/Cs(2)CO(3)/MeCN at 50 degrees C followed by heating to 80 degrees C resulted in N-N' bond cleavage to the corresponding carbamates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5ef37cec7c980da220948c7de5cfa113 https://doi.org/10.1002/chin.201019052 Zobrazit plný text záznamu Plný text