Single-crystal EPR spectra of the high-spin [Co(TMC)(CH3CN))](ClO2)2 complex

Autor:	Mark Wicholas, Claudia Zanchini
Rok vydání:	1990
Předmět:	Crystallography law Chemistry General Physics and Astronomy Macrocyclic ligand Physical and Theoretical Chemistry Spin (physics) Anisotropy Electron paramagnetic resonance Single crystal Spectral line law.invention
Zdroj:	Chemical Physics Letters. 171:114-118
ISSN:	0009-2614
DOI:	10.1016/0009-2614(90)80059-m
Popis:	A single-crystal EPR study of [Co(TMC)(CH3CH)](ClO4)2 is reported. The observed g values are highly anisotropic: g1 = 7.1(2), g2 = 2.1(2), g3 = 1.4(2). The angular-overlap model allowed an effective rationalization of the data indicating that the g-tensor pattern is mainly determined by the in-plane σ interaction of the tetraaza macrocyclic ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5edc9e465ae248a6777ebad0ce592097 https://doi.org/10.1016/0009-2614(90)80059-m Zobrazit plný text záznamu