Benzodicarbene-bridged dinuclear complexes as building blocks for metalosupramolecular architectures
| Autor: | F. Ekkehardt Hahn, Christian Schulte to Brinke, Markus Schmidtendorf |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Chemistry
Organic Chemistry Inorganic chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Rhodium Inorganic Chemistry Metal chemistry.chemical_compound visual_art Halogen Materials Chemistry visual_art.visual_art_medium Molecule Iridium Self-assembly Physical and Theoretical Chemistry Acetonitrile |
| Zdroj: | Journal of Organometallic Chemistry. 751:620-627 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2013.08.001 |
| Popis: | Dinuclear benzodicarbene-bridged iridium(III) and rhodium(III) complexes [Cp*(Cl)2M(benzodicarbene)M(Cl)2Cp*] [3]–[5] have been synthesized from N,N′,N″,N″-tetraalkylbenzobisimidazolium salts and [MCp*(Cl)2]2 via the Ag2O method. Molecular structure determinations show an anti-arrangement of the {MCp*} moieties relative to the bridging dicarbene ligand. Complexes [3]−[5] have been dehalogenated once at each metal atom which led to the formation of tetranuclear rectangles [7](BF4)4–[9](BF4)4 featuring two benzodicarbene and two dichloro bridges between the metal centers. Removal of all halogen atoms from complexes [3] and [4] with AgBF4 in acetonitrile yielded dinuclear iridium(III) and rhodium(III) complexes of type [Cp*(MeCN)2M(benzodicarbene)M(MeCN)2Cp*](BF4)2 [10](BF4)4–[11](BF4)4. |
| Databáze: | OpenAIRE |
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