Raman Spectral Study of Vibrational Relaxation of the CN Stretching Band of Acetonitrile and Benzonitrile
| Autor: | Anusree Ghosh, T. N. Misra, S.K Nandy, Debajyoti Bhattacharjee |
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| Rok vydání: | 1996 |
| Předmět: |
Isotropy
Analytical chemistry London dispersion force chemistry.chemical_compound Benzonitrile symbols.namesake chemistry Physics::Atomic and Molecular Clusters Vibrational energy relaxation symbols General Materials Science Physics::Chemical Physics Acetonitrile Raman spectroscopy Spectroscopy Line (formation) |
| Zdroj: | Journal of Raman Spectroscopy. 27:457-461 |
| ISSN: | 0377-0486 |
| DOI: | 10.1002/(sici)1097-4555(199606)27:6<457::aid-jrs978>3.0.co;2-3 |
| Popis: | Raman spectroscopic studies on acetonitrile and benzonitrile as the liquids and in dilute solutions were used to investigate the vibrational relaxation processes which lead to broadening of the C≡N stretching vibrational band. Line widths of isotropic Raman spectra in a number of solvents revealed the quantitative dependence of vibrational relaxation rate on the hydrodynamic and dispersion forces. |
| Databáze: | OpenAIRE |
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