Aqua(5,6-dimethyl-1,10-phenanthroline-N,N')(malonato-O,O')copper(II) hydrate

Autor:	J. L. Briansó-Penalva, E. Mollins, G. Medina-Dickinson, Lena Ruiz-Ramirez, Rafael Moreno-Esparza, Laura Gasque
Rok vydání:	1999
Předmět:	Stereochemistry Phenanthroline General Medicine Crystal structure Ring (chemistry) General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound Crystallography Malonate chemistry Moiety Carboxylate Hydrate Coordination geometry
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 55:158-160
ISSN:	0108-2701
DOI:	10.1107/s0108270198009937
Popis:	Each copper ion in the title complex, [Cu(C 3 H 2 O 4 )(C 14 H 12 N 2 )(H 2 O)].H 2 O displays a slightly distorted square-pyramidal coordination geometry, where the water molecule is in the apical position and two malonate O atoms and the phenanthroline N atoms define the base. The five-membered chelate ring defined by the phenanthroline molecule and the Cu atom is nearly planar with only slight distortion, while the ring defined by the malonate moiety and the Cu atom displays an envelope conformation. Hydrogen-bond and π-π * interactions define the crystal packing.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5eb73ebf735903bc34bee6fe0b53156f https://doi.org/10.1107/s0108270198009937 Zobrazit plný text záznamu Plný text