Efficient selective synthesis of 2-substituted indoles from complex-base-promoted arynic cyclisations

Autor:	Catherine Kuehm-Caubère, Bruno Pfeiffer, Ivan Rodriguez, Pierre Renard, Paul Caubere
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Stereochemistry Chemistry Aryl Base (exponentiation) Combinatorial chemistry
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :2857-2862
ISSN:	1364-5463 0300-922X
DOI:	10.1039/a702548c
Popis:	2-Substituted indoles have been efficiently obtained by selective arynic cyclisation of halogenated aryl imines of methyl ketones in the presence of the complex-base NaNH2–ButONa and by PhCH2SH–AlCl3 opening of tetrahydrothiopyranoindoles also obtained from arynic cyclisation of imines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5e99b1d0d67d9c2130c5e1aa31675ba0 https://doi.org/10.1039/a702548c Zobrazit plný text záznamu