Controlling photocatalytic reduction of CO2 in Ru(ii )/Re(i ) dyads via linker oxidation state
| Autor: | Thomas Auvray, Garry S. Hanan, Emile E. DeLuca, Maria B. Ezhova, Christopher M. Brown, Michael O. Wolf |
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| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Chemistry Metals and Alloys General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Catalysis 3. Good health 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal Reduction (complexity) Oxidation state visual_art Materials Chemistry Ceramics and Composites Photocatalysis visual_art.visual_art_medium Electronic communication Linker |
| Zdroj: | Chemical Communications. 56:10750-10753 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d0cc04597g |
| Popis: | Electronic communication between the linked metal centers in Ru(II)–Re(I) dyads is tuned using the oxidation state (S and SO2) of sulfur-bridged ligands. Higher catalytic activity is seen for the SO2-bridged dyad in the photocatalytic reduction of CO2. |
| Databáze: | OpenAIRE |
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