Alkaline dechlorination of poly(vinyl chloride) in organic solvents under mild conditions

Autor:	Tomoyuki Ichiki, Jie Chen, Toshifumi Tanimura, Makoto Yamaye, Takeshi Yamanobe, Tetsutaro Yoshinaga, Masahiko Ogata, Hiroshi Fujino, Taketoshi Kito
Rok vydání:	2004
Předmět:	Vinyl alcohol Polymers and Plastics Inorganic chemistry chemistry.chemical_element Condensed Matter Physics Vinyl chloride Solvent chemistry.chemical_compound Polyvinyl chloride Hydrolysis chemistry Mechanics of Materials Materials Chemistry Chlorine Alkaline hydrolysis Chemical decomposition
Zdroj:	Polymer Degradation and Stability. 86:541-547
ISSN:	0141-3910
DOI:	10.1016/j.polymdegradstab.2004.06.008
Popis:	A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under atmospheric pressure, a DD of 98–99% was accomplished in the hydrolysis with NaOH in dimethylsulfoxide at 80 °C for 1–3 h. The resulting hydrolysis product is poly(vinyl alcohol) with a very small chlorine content. Sodium chloride was the only by-product and no other harmful products such as dioxins were formed. Possible solvent recycling mainly depends on controlled use of water.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5e7fbd55cd3ed35ccb9b70031dfc66ab https://doi.org/10.1016/j.polymdegradstab.2004.06.008 Zobrazit plný text záznamu Full Text from ScienceDirect