Nano-Thick Amorphous Oxide Layer Produced by Plasma on Type 316L Stainless Steel for Improved Corrosion Resistance Under Plastic Deformation
| Autor: | Megan Mahrokh Dorri, Stéphane Turgeon, Diego Mantovani, Pascale Chevallier, Maxime Cloutier |
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| Rok vydání: | 2018 |
| Předmět: |
010302 applied physics
Materials science General Chemical Engineering Amorphous oxide 02 engineering and technology General Chemistry Plasma 021001 nanoscience & nanotechnology Microstructure 01 natural sciences Chloride Corrosion 0103 physical sciences Nano medicine General Materials Science Crystallite Composite material 0210 nano-technology Layer (electronics) medicine.drug |
| Zdroj: | Corrosion. 74:1011-1022 |
| ISSN: | 1938-159X 0010-9312 |
| Popis: | Localized corrosion constitutes a major concern in medical devices made of stainless steel. The conventional approach to circumvent such a problem is to convert the surface polycrystalline microstructure of the native oxide layer to an amorphous oxide layer, a few micrometers thick. This process cannot, however, be used for devices such as stents that undergo plastic deformation during their implantation, especially those used in vascular surgery for the treatment of cardiac, neurological, and peripheral vessels. This work explores the feasibility of producing a nano-thick plastic-deformation resistant amorphous oxide layer by plasma-based surface modifications. By varying the plasma process parameters, oxide layers with different features were produced and their properties were investigated before and after clinically-relevant plastic deformation. These properties and the related corrosion mechanisms were mainly evaluated using the electrochemical methods of open-circuit potential, cyclic potentiodynamic polarization, and electrochemical impedance spectroscopy. Results showed that, under optimal conditions, the resistance to corrosion and to the permeation of ions in a phosphate buffered saline, even after deformation, was significantly enhanced. |
| Databáze: | OpenAIRE |
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