Chemiluminescence in the autooxidation of dihydroxyphenylalanine
Autor: | G. N. Bogdanov, V. N. Shtol’ko |
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Rok vydání: | 1972 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 21:2637-2640 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00849829 |
Popis: | 1. In the oxidation of dihydroxyphenylalanine in alkaline medium, chemiluminescence was detected in the region of 450–600 nm with a maximum at 530 nm. The step of cyclization, leading to the formation of 5,6-dihydroxyindole, proved responsible for the luminescence. 2. The kinetic curve of the change in the luminescence is described by a second-order equation of autocatalysis. |
Databáze: | OpenAIRE |
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