Reaction of hydrogen peroxide with hexaaquacobalt(III) perchlorate

Autor:	Robert B. Jordan, Grant W. Wangila
Rok vydání:	2006
Předmět:	Inorganic Chemistry Hydrolysis Perchlorate chemistry.chemical_compound Reaction rate constant chemistry Materials Chemistry Physical chemistry Organic chemistry Rate equation Physical and Theoretical Chemistry Hydrogen peroxide
Zdroj:	Inorganica Chimica Acta. 359:3177-3182
ISSN:	0020-1693
Popis:	The reaction of Co ( OH 2 ) 6 3 + with H2O2 in 1.0 M HClO4/LiClO4 was found to be first-order in both reactants and the [H+] dependence of the second-order rate constant is given by k2obs = b/[H+], b at 25 °C is 26.4 ± 0.5 s−1. The rate law shows a simple inverse dependence on [H+] that is consistent with a rapidly maintained equilibrium between Co ( OH 2 ) 6 3 + and its hydrolyzed form Co(H2O)5(OH)2+, followed by the rate controlling step, i.e. oxidation of H2O2 by Co(H2O)5(OH)2+.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5e4e34a9c08baa5877904cc36509f382 https://doi.org/10.1016/j.ica.2006.03.005 Zobrazit plný text záznamu Full Text from ScienceDirect