Thermal Stability of Titanium-Molybdenum and Titanium-Copper Bilayer Thin Films on Alumina

Autor: Stephen W. Russell, Jian Li, J. W. Strane, J. W. Mayer
Rok vydání: 1992
Předmět:
Zdroj: Crucial Issues in Semiconductor Materials and Processing Technologies ISBN: 9789401052030
DOI: 10.1007/978-94-011-2714-1_31
Popis: The stability of titanium-copper and titanium-molybdenum bimetallic layers on A12O3 was studied over the temperature range 700–900 C using vacuum furnace annealing and rapid thermal annealing (RTA). The molybdenum-titanium bilayer was stable over the entire temperature range. These films exhibited only slight intermixing of the metallic layers and had no evidence of any interaction between the bilayer and substrate. High temperature processing of copper on alumina often results in clustering and spheroidization of the copper film. However, our results showed that titanium and copper layers reacted to form a planar, polycrystalline intermetallic layer. The reacted Ti-Cu product interacted with the alumina substrate to promote adhesion, thereby suppressing spheroidization of the thin film. These results were independent of annealing profile; RTA and furnace heat treatments produced films with similar thermal stability.
Databáze: OpenAIRE