Trimethylsilylmethyl and methyl compounds of manganese, cobalt and uranium
| Autor: | Geoffrey Wilkinson, Elin R. Sigurdson, Ernesto Carmona-Guzman, Konstantinos Mertis, Richard A. Andersen |
|---|---|
| Rok vydání: | 1975 |
| Předmět: |
Organic Chemistry
Inorganic chemistry chemistry.chemical_element Tetramethylethylenediamine Manganese Uranium Biochemistry Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Materials Chemistry visual_art.visual_art_medium Lithium Physical and Theoretical Chemistry Cobalt Carbon Tetrahydrofuran Nuclear chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 99:C19-C20 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)86378-0 |
| Popis: | Thermally stable alkylmanganese(II) compounds, Mn(CH2R)2 R = SiMe3, CMe3 and CMe2Ph have been isolated; and oxidation with dioxygen shown to give unstable green alkylmanganese(IV) compounds; lithium alkylate anions of manganese(II), cobalt(II) and uranium(IV) have also been isolated as tetrahydrofuran or tetramethylethylenediamine solvates, the uranium compounds, e.g. Li2 [U(CH2SiMe3)6](tmed)7 being the first uranium complexes with more than one metal to carbon σ-bond. |
| Databáze: | OpenAIRE |
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