Simultaneous Multiwavelength Detection System for Liquid Chromatography

Autor:	Leon N. Klatt
Rok vydání:	1979
Předmět:	Data processing Rapid scan Accuracy and precision Chromatography Chemistry Detector Radiant energy General Medicine Column (database) Minicomputer Analytical Chemistry law.invention Chromatographic separation law
Zdroj:	Journal of Chromatographic Science. 17:225-235
ISSN:	1945-239X 0021-9665
DOI:	10.1093/chromsci/17.4.225
Popis:	A simultaneous multi-wavelength detection system for liquid chromatography is described. The system consists of a rapid scan sectrometer with a uv silicon vidicon target as radiant energy detector, a minicomputer, a programming language, and the requisite chromatographic hardware. Algorithms required for a real-time data processing capability are described. Multi-wavelength data retained during a chromatographic separation are summarized as an absorbance-wavelength-time surface. The ability to identify components unresolved by the chromatographic column is demonstrated. Solutes unresolved by the column can be quantitated with a precision and accuracy equal to that observed for solutes resolved by the column. The use of this detection system to qualitatively assess compositional changes in a coal derived oil as a function of process, as well as the limitations of the system and required improvements are discussed. 11 figures, 4 tables.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5e251f7e094f1452e77cbd6115156958 https://doi.org/10.1093/chromsci/17.4.225 Zobrazit plný text záznamu