Optical rotatory dispersion and circular dichroism of diastereomeric S-allyl-L-cysteine S-oxides

Autor: Kurt Mislow, Paul D. Henson
Rok vydání: 1969
Předmět:
Zdroj: Journal of the Chemical Society D: Chemical Communications. :413
ISSN: 0577-6171
Popis: The perturbing effect of the allyl group on the chiroptical properties of sulphoxides is strikingly manifested in the observation that the diastereomers of S-allyl-L-cysteine S-n-propyl-L-cysteine S-oxide with the same configuration at sulphur have virtually mirror-image o.r.d. and c.d. curves, whereas those with opposite configurations at sulphur have closely matching o.r.d. and c.d. curves.
Databáze: OpenAIRE