Molecular assembly of a pyridine functionalized janusarene

Autor: Chaojun Lin, Luoyi Fan, Haonan Shi, Yanpeng Zhu, Bangyuan Xiong, Jiaobing Wang, Jiajian Gu, Zhibo Yin
Rok vydání: 2022
Předmět:
Zdroj: Chinese Chemical Letters. 33:280-282
ISSN: 1001-8417
DOI: 10.1016/j.cclet.2021.06.057
Popis: We describe a janusarene derivative PyJ, which forms micrometer-scale one-dimensional metallo-supramolecular polymer through coordination driven self-assembly. PyJ is a well-preorganized dodecatopic pyridyl ligand built on a hexaphenylbenzene platform. The two-face structural feature of PyJ allows for a delicate control over multiple Py-Ag+-Py coordination interactions, leading to assembled structure of PyJ-Ag+, which was characterized by dynamic light scattering, atomic force microscopy, and transmission electron microscopy.
Databáze: OpenAIRE