Non-catalytic partial oxidation of bio-oil to synthesis gas for distributed hydrogen production
| Autor: | Anthony M. Dean, Stefan Czernik, Robert J. Evans, Richard J. French, Shannon McKibben, Jonathan R. Marda, Joelle DiBenedetto |
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| Rok vydání: | 2009 |
| Předmět: |
Volatilisation
Hydrogen Renewable Energy Sustainability and the Environment Energy Engineering and Power Technology chemistry.chemical_element Raw material Condensed Matter Physics Catalysis chemistry.chemical_compound Fuel Technology chemistry Chemical engineering Methanol Partial oxidation Hydrogen production Syngas |
| Zdroj: | International Journal of Hydrogen Energy. 34:8519-8534 |
| ISSN: | 0360-3199 |
| Popis: | A system has been developed for the volatilization and conversion of a bio-oil mixed with methanol to synthesis gas via non-catalytic partial oxidation (NPOX) using an ultrasonic nozzle to feed the mixture. Such a process would be ideal for distributed H2 production. The feedstock used was derived from poplar wood. The effects of both temperature (from 625 to 850 °C) and added oxygen (effective O:C ratio from 0.7 to 1.6) on the yields of CO and H2 have been explored. High yields of CO (between 50% and 70% of the maximum possible from the bio-oil) have been observed. Hydrogen yields are much lower (∼25% of the maximum possible). However, the water formed during NPOX can be used to generate additional H2. The bio-oil carbon to gas conversion is typically between 85% and 95% for optimal conditions. Due to this significant conversion, lower catalyst loadings are expected to be required for the downstream processing. |
| Databáze: | OpenAIRE |
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