On the mechano-chemical destruction of polyethylene terephthalate by vibratory milling
| Autor: | Cristofor Simionescu, Claudia Neguleanu, C. Vasiliu Oprea |
|---|---|
| Rok vydání: | 1970 |
| Předmět: |
Inert
chemistry.chemical_classification Materials science Condensation polymer Polymers and Plastics Organic Chemistry General Physics and Astronomy Chemical destruction Polymer Chemical reaction Polyester Hydrolysis chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Polyethylene terephthalate |
| Zdroj: | European Polymer Journal. 6:181-198 |
| ISSN: | 0014-3057 |
| DOI: | 10.1016/0014-3057(70)90151-5 |
| Popis: | The paper is concerned with the behaviour of polyethylene terephthalate in the process of vibratory milling. This polymer belongs to the class of heterochain macromolecular compounds; depending on the mechanical and other working conditions (medium, temperature, etc.), it may exhibit various chemical reactions. In inert media (gaseous or liquid) and in the absence of humidity, mechanochemical destruction is radically initiated. The presence of small quantities of water favours hydrolysis, activated mechano-chemically. The functional end groups (carboxylic and hydroxylic) in the polyester chain permit the initiation, for the first time in the field of mechano-chemistry of macromolecular compounds, of the processes of polycondensation by using diamines in the reaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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