Emission analysis of RE3+ (Eu3+, Tb3+ & Ho3+): B2O3-BaO-LiF/AIF3 glasses

Autor: S. Buddhudu, B. H. Rudramadevi
Rok vydání: 2009
Předmět:
Zdroj: Indian Journal of Physics. 83:313-323
ISSN: 0974-9845
0019-5480
DOI: 10.1007/s12648-009-0118-8
Popis: We report here the luminescence spectra of certain rare earth ions (Eu3+, Tb3+ & Ho3+) doped B2O3-BaO-LiF/AiF3 based on the measurements of emission and decay curves of prominent emission transitions. For both the reference host glasses, FTIR, XRD, DTA-TG profiles have been recorded to understand their structural and thermal properties. Eu3+ doped glasses have shown five emission transitions of 5D0 → 7F01,2,3 & 4 located at 580nm, 593nm, 615nm, 655nm and 704nm respectively with an excitation at λexci = 392 nm (7F0 → 5L6). Also under an UV source, these europium glasses have displayed a bright red emission from their surfaces. Tb3+ glasses have exhibited four emission bands of 5D4 → 7F6,5,4,3 at 491nm, 547nm, 588nm and 625nm respectively with an excitation at λexci = 376 nm (7F6 → 5G6). Intense green emission from the glass surfaces has been noticed upon exposure to the UV source. Prominently bluish-green emission has been noticed from the surfaces of the holmium glasses under an UV source and same emission transition (5F4 → 5I8) at 519 nm with an excitation at λexci = 389 nm (5I8 − 5G4) has also been obtained from their measured emission spectra. For all the prominent emissions of the rare earth glasses, decay curves have been measured to compute their lifetimes.
Databáze: OpenAIRE
Externí odkaz: