Electrochemical oxidation of substituted 3,4-dihydro-2-pyridones at a rotating graphite electrode with a ring

Autor:	V. P. Kadysh, Ya. P. Stradyn, Yu. E. Pelcher, Ya. V. Ogle, G. Ya. Dubur
Rok vydání:	1984
Předmět:	Electrolysis Chemistry Organic Chemistry Inorganic chemistry Electrochemistry Ring (chemistry) law.invention chemistry.chemical_compound Ultraviolet visible spectroscopy law Electrode Anhydrous Graphite Acetonitrile
Zdroj:	Chemistry of Heterocyclic Compounds. 20:73-77
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00505855
Popis:	Using the method of a rotating disk (graphite) electrode with a ring, UV spectroscopy, and prolonged electrolysis, it has been shown that the first stage of the electrochemical oxidation of substituted 3,4-dihydro-2-pyridones in anhydrous acetonitrile corresponds to a two-electron process taking place by an ECE mechanism and leads to the formation of the corresponding substituted 2-pyridones. The potentials of the electrochemical oxidation of the 3-cyano and 3-carbamoyl derivatives of the reduced forms and the potentials of the electroreduction of the corresponding oxidized compounds have been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5ddce8305cd96a021d27bbd0c3f5be72 https://doi.org/10.1007/bf00505855 Zobrazit plný text záznamu Full text from SpringerLink