Intramolecular C-H...N interactions in 1-vinyl- and 1,1?-divinyl-2,2?-biimidazolyls according to the data of1H and13C NMR

Autor: A. V. Afonin, L. V. Baikalova, V. K. Voronov, E. S. Domnina
Rok vydání: 1990
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:2489-2493
ISSN: 1573-9171
0568-5230
Popis: The specific intramolecular interaction between the α-proton of the vinyl group and the pyridine nitrogen atom of the second imidazole ring, similar to the hydrogen bond, is accomplished in 1-vinyl- and 1,1′-divinyl-2,2′-biimidazolyls. In 1-vinyl-2,2'-biimidazolyl, the available NH-proton of the 2'-imidazole ring is localized at the nitrogen atom in the anti orientation in relation to the vinyl group.
Databáze: OpenAIRE