Intramolecular C-H...N interactions in 1-vinyl- and 1,1?-divinyl-2,2?-biimidazolyls according to the data of1H and13C NMR
Autor: | A. V. Afonin, L. V. Baikalova, V. K. Voronov, E. S. Domnina |
---|---|
Rok vydání: | 1990 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:2489-2493 |
ISSN: | 1573-9171 0568-5230 |
Popis: | The specific intramolecular interaction between the α-proton of the vinyl group and the pyridine nitrogen atom of the second imidazole ring, similar to the hydrogen bond, is accomplished in 1-vinyl- and 1,1′-divinyl-2,2′-biimidazolyls. In 1-vinyl-2,2'-biimidazolyl, the available NH-proton of the 2'-imidazole ring is localized at the nitrogen atom in the anti orientation in relation to the vinyl group. |
Databáze: | OpenAIRE |
Externí odkaz: |