Intramolecular nucleophile-assisted cleavage of organosilane cation radicals

Autor:	Samir Farid, Joshua L. Goodman, Ian R. Gould, Joseph P. Dinnocenzo, W. P. Todd
Rok vydání:	1993
Předmět:	Reaction mechanism Intramolecular reaction Stereochemistry Chemistry Radical Organic Chemistry Photochemistry Biochemistry Electron transfer Nucleophile Intramolecular force Drug Discovery Nucleophilic substitution Solvent effects
Zdroj:	Tetrahedron Letters. 34:2863-2866
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)60466-5
Popis:	Organosilane cation radicals which have tethered nucleophiles are found to undergo rapid intramolecular nucleophilic substitution in both high and low polarity solvents. This reaction competes with both separation and return electron transfer within the primary ion radical pair generated by photoinduced bimolecular electron transfer. These results demonstrate the ability to effect ion radical substitutions in low polarity solvents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5da8b11dd4f864be6bd4d1b014c43ec4 https://doi.org/10.1016/s0040-4039(00)60466-5 Zobrazit plný text záznamu