Generation, characterization, and properties of iron-silylene and iron-silene cationic complexes in the gas phase
| Autor: | R. Bakhtiar, D. B. Jacobson |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
Silanes
Inorganic chemistry Cationic polymerization Silylene General Chemistry Photochemistry Mass spectrometry Biochemistry Catalysis Dissociation (chemistry) Fourier transform ion cyclotron resonance chemistry.chemical_compound Colloid and Surface Chemistry Reaction rate constant chemistry Molecule |
| Zdroj: | Journal of the American Chemical Society. 115:10830-10844 |
| ISSN: | 1520-5126 0002-7863 |
| Popis: | Generation, characterization, and properties of iron-silylene (Fe=SiRR') and iron-silene (Fe(CH 2 =SiRR')) cations (R, R'=H, CH 3 ) are describe in the gas phase by using Fourier transform mass spectrometry (FTMS). Iron-(silylene/silene) cations were formed by reaction of Fe + with appropriate silanes. Structures of these ions were probed by using both collision-activated dissociation (CAD) and ion/molecule reactions. CAD failed to yield structural information; however, reaction with isotopically labeled ethene provides compelling evidence for formation of ironsilene and iron-silylene species |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|