2,2,6,6-Tetramethylpiperidinium triflate (TMPT): a highly selective and self-separated catalyst for esterification

Autor:	Lan Gao, Xiaochun Tao, Yongmin Huang, Taoping Liu
Rok vydání:	2016
Předmět:	Steric effects 010405 organic chemistry Chemistry Organic Chemistry 010402 general chemistry Highly selective 01 natural sciences Biochemistry 0104 chemical sciences Catalysis Drug Discovery Organic chemistry Reaction system Selectivity Trifluoromethanesulfonate
Zdroj:	Tetrahedron Letters. 57:4905-4909
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2016.09.061
Popis:	An eco-friendly and readily accessible 2,2,6,6-tetramethylpiperidinium triflate was found as highly-selective and self-separated catalyst for esterification under solvent-free condition. The X-ray crystallography revealed that it formed a ‘hydrophobic wall’ which could effectively eliminate the generated water from the reactive sites. Moreover, it could precipitate from the reaction system with excellent recovery ratio (>99%) and be reused for ten times without any significant loss of activity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d688be2e1f2e9990273d93ec9ca4cee https://doi.org/10.1016/j.tetlet.2016.09.061 Zobrazit plný text záznamu Full Text from ScienceDirect