Detonation Characteristics of Plastic Explosives Based on Attractive Nitramines with Polyisobutylene and Poly(methyl methacrylate) Binders
Autor: | Svatopluk Zeman, Waldemar A. Trzciński, Pavel Vávra, Jiri Pachman, Zbyněk Akštein, Ahmed Elbeih |
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Rok vydání: | 2012 |
Předmět: |
Materials science
Physics and Astronomy (miscellaneous) Explosive material Detonation Poly(methyl methacrylate) law.invention chemistry.chemical_compound Matrix (mathematics) Brisance Chemical engineering chemistry law visual_art visual_art.visual_art_medium Imidazole Organic chemistry Plastic explosive Methyl methacrylate |
Zdroj: | Journal of Energetic Materials. 30:358-371 |
ISSN: | 1545-8822 0737-0652 |
DOI: | 10.1080/07370652.2011.585216 |
Popis: | Four highly brisant nitramines, RDX (1,3,5-trinitro-1,3,5-triazinane), HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocane), BCHMX (cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d]imidazole), and ϵ-HNIW (ϵ-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane), were studied as extruded plastic explosives bonded by two plastic matrices based on polyisobutylene (C4 matrix) and poly-methylmethacrylate (plasticized by dioctyl-adipate) binders. The detonation velocities, D, were measured experimentally. Detonation parameters were also calculated by means of the Kamlet and Jacobs method and CHEETAH and EXPLO5 codes. These detonation parameters showed that plastic-bonded explosives (PBXs) based on BCHMX are more powerful explosives than those based on RDX. The Urizar coefficient for poly(methyl methacrylate) binder was also calculated. |
Databáze: | OpenAIRE |
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