Tertiary amines as a C1 synthon: metal-free synthesis of quinolines and 2-substituted quinolines via [3+2+1] aerobic cyclization and C–N bond cleavage

Autor: Jing-Yuan Liu, Zhen-Ying Wang, Qiang Li, Dacheng Li, Jianmin Dou
Rok vydání: 2023
Předmět:
Zdroj: New Journal of Chemistry. 47:5155-5159
ISSN: 1369-9261
1144-0546
DOI: 10.1039/d2nj04119g
Popis: An I2-mediated aerobic cyclization reaction of anilines, alkynes, and tertiary amine has been reported. In this protocol, a novel strategy for the synthesis of quinolines using tertiary amines as a C1 synthon via C–N bond cleavage.
Databáze: OpenAIRE