Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

Autor:	Brian W. Skelton, N. T. Gorham, Robert C. Woodward, Jonathan G. MacLellan, Timothy G. St. Pierre, Massimiliano Massi, Benjamin Hugh Fraser, Todd R. Scicluna
Rok vydání:	2010
Předmět:	Crystallography chemistry.chemical_compound Hydrogen Octahedron Chemistry Stereochemistry Pyridine chemistry.chemical_element General Materials Science General Chemistry Crystal structure Condensed Matter Physics Supramolecular assembly
Zdroj:	CrystEngComm. 12:3422
ISSN:	1466-8033
Popis:	CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl2], the disubstituted [Co(H2L)2][PF6]2, and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [{Co(H2L)2}(H2L)4][PF6]2, as illustrated by X-ray crystal structure analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d3a92e4626f51ece68171ae449ccfe4 https://doi.org/10.1039/c0ce00036a Zobrazit plný text záznamu