Methylation and hydroxymethylation of allylic alcohols via radical cyclization. Methodology for stereoselective construction of an aliphatic chain in application to sterol synthesis

Autor:	Guenther Snatzke, Andrzej Zarecki, Jerzy Wicha, Alicja Kurek-Tyrlik
Rok vydání:	1990
Předmět:	Allylic rearrangement chemistry.chemical_compound Intramolecular reaction Chemistry Stereochemistry Organic Chemistry Regioselectivity Free-radical reaction Stereoselectivity Ether Methylation Radical cyclization
Zdroj:	The Journal of Organic Chemistry. 55:3484-3492
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00298a020
Popis:	Syntese de cholestene-5 diol-3β,25 a partir de methoxy-6β cyclo-3α,5α pregnene-17 (20) oate-21 d'ethyle via une cyclisation intramoleculaire du radical libre genere a partir de l'intermediaire [bromomethyl dimethyl siloxy]-21 methoxy-6β cyclo-3α,5α pregnene-17 (20)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d380862a509ce6d43da942f4ac28e07 https://doi.org/10.1021/jo00298a020 Zobrazit plný text záznamu