Reactions of Ir(CO)(H)(P(p-tolyl)3)3 with SO2 and O2 Mixtures and with H2SO4, Formation of a Sulfate-Bridged Dimer, and Crystal and Molecular Structure of Ir(CO)(H)(SO2)(P(p-tolyl)3)2

Autor: Melvyn Rowen Churchill, Jim D. Atwood, Cynthia A. Miller, T.S. Janik
Rok vydání: 1996
Předmět:
Zdroj: Inorganic Chemistry. 35:3683-3686
ISSN: 1520-510X
0020-1669
DOI: 10.1021/ic951249y
Popis: Reactions of HIr(CO)(P(p-tolyl)3)3 with SO2, O2, mixtures of SO2 and O2, and H2SO4 are described. Reactions with mixtures of SO2/O2 and with H2SO4 lead to a common product, Ir2H4(μ-SO4)(P(p-tolyl)3...
Databáze: OpenAIRE