Reactions of Ir(CO)(H)(P(p-tolyl)3)3 with SO2 and O2 Mixtures and with H2SO4, Formation of a Sulfate-Bridged Dimer, and Crystal and Molecular Structure of Ir(CO)(H)(SO2)(P(p-tolyl)3)2
Autor: | Melvyn Rowen Churchill, Jim D. Atwood, Cynthia A. Miller, T.S. Janik |
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Rok vydání: | 1996 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 35:3683-3686 |
ISSN: | 1520-510X 0020-1669 |
DOI: | 10.1021/ic951249y |
Popis: | Reactions of HIr(CO)(P(p-tolyl)3)3 with SO2, O2, mixtures of SO2 and O2, and H2SO4 are described. Reactions with mixtures of SO2/O2 and with H2SO4 lead to a common product, Ir2H4(μ-SO4)(P(p-tolyl)3... |
Databáze: | OpenAIRE |
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