New low-dimensional molecular conductors: α′′-(BEDO-TTF)2Cl·3H2O andθ-(BDH-TTP)2(Br0.67Cl0.33)·3H2O

Autor:	S. S. Khasanov, Leokadiya V. Zorina, Rimma P. Shibaeva, Sergey V. Simonov
Rok vydání:	2011
Předmět:	Crystallography Materials science Physics and Astronomy (miscellaneous) Hydrogen bond Electrical resistivity and conductivity Halogen X-ray crystallography General Physics and Astronomy Molecule Crystal structure Electronic band structure Ion
Zdroj:	Low Temperature Physics. 37:744-748
ISSN:	1090-6517 1063-777X
DOI:	10.1063/1.3665894
Popis:	X-ray single-crystal diffraction studies of two new molecular conductors α′′-(BEDO-TTF)2Cl·3H2O and θ-(BDH-TTP)2(Br0.67Cl0.33)·3H2O are reported. Both crystals have a layered structure in which conducting layers of organic BEDO-TTF or BDH-TTP π-electron donors are separated by complex anion layers. The anion layers consist of honeycomb networks of Cl− (Br−) halogen anions and water molecules, which are stable owing to the formation of hydrogen bonds. Calculations of the electron band structure of these crystals show that metallic conductivity is to be expected in the organic α′′-(BEDO-TTF) and θ-(BDH-TTP) layers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d2f0fce4212b780a46476db7b2595cc https://doi.org/10.1063/1.3665894 Zobrazit plný text záznamu