ChemInform Abstract: DITERPENE CHEMISTRY. VII. SULFUR-CONTAINING DERIVATIVES OF LABDA-8(17),14-DIEN-13-OL (MANOOL)

Autor:	PK Grant, Htl Liau
Rok vydání:	1978
Předmět:	Sodium borohydride chemistry.chemical_compound Silver nitrate chemistry Organic chemistry chemistry.chemical_element General Medicine Diterpene Sulfur containing Sulfur
Zdroj:	Chemischer Informationsdienst. 9
ISSN:	0009-2975
DOI:	10.1002/chin.197851336
Popis:	The reactions of manool derivatives with sulfurated sodium borohydride to give sulfur-containing diterpene derivatives are reported. 13,17-Epithio-8,13-epoxy-14,15-dinorlabdane (12), the sulfur analogue of the highly odiferous compound 8,13:13,17-diepoxy-14,15 dinorlabdane (4), has been synthesized. A simple but very effective use of silver nitrate to prevent double-bond participation in an acetalization reaction is reported.
Databáze:	OpenAIRE
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