Autor:	E. S. Petrov, Yu. G. Noskov
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Reaction mechanism chemistry Hydride Kinetics Polymer chemistry Cationic polymerization General Chemistry Triphenylphosphine Photochemistry Carbonylation Styrene Catalysis
Zdroj:	Russian Chemical Bulletin. 50:1839-1843
ISSN:	1066-5285
DOI:	10.1023/a:1014382013055
Popis:	The kinetics of the catalytic reaction of styrene with CO and n-butanol in the Pd(dba)2—TsOH—Ph3P system in dioxane (383 E) was studied. The initial rates of accumulation of regioisomeric products (butyl 2- and 3-phenylpropionates) were measured as functions of the CO pressure, reactant concentrations, and the catalytic system components. A kinetic model of the process and a hydride mechanism with the HPd(Ph3P)3+ cationic complex acting as a key intermediate were proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d15e878b706081ddf8461651abd7025 https://doi.org/10.1023/a:1014382013055 Zobrazit plný text záznamu Full text from SpringerLink