Reversibility of the lithium—vanadium bronze structure when cycled

Autor:	O. Yu. Grigor’eva, Alexander M. Skundin, A. K. Ivanov-Shitz, S. V. Pushko
Rok vydání:	2000
Předmět:	Intercalation (chemistry) Inorganic chemistry Vanadium chemistry.chemical_element Crystal structure engineering.material Electrochemistry Lithium perchlorate Amorphous solid chemistry.chemical_compound chemistry engineering Lithium Bronze
Zdroj:	Russian Journal of Electrochemistry. 36:802-805
ISSN:	1608-3342 1023-1935
DOI:	10.1007/bf02757686
Popis:	Positive electrodes of secondary lithium batteries, based on Li1 + xV3O8 obtained by the alcoxytechnology, are studied. As lithium intercalates, the initial crystalline bronze turns amorphous, remaining single-phase. An increase in the lithiation degreex leads to an almost linear decrease in parametera and increase in parametersb andc of the bronze crystal lattice; the changes are quite reversible when cycling. A noticeable degradation of electric characteristics of electrodes is unrelated to irreversible structural changes and may be explained by the formation of passive films on the bronze surface.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d15d95ee9cf9bbe33d8c9fc1cb1fdda https://doi.org/10.1007/bf02757686 Zobrazit plný text záznamu Full text from SpringerLink