Substituent effects of phosphonate groups electronic repartition of π-conjugated ferrocene analogues of stilbene
| Autor: | Gérard F. Lanneau, Richard Frantz, Jean-Olivier Durand |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
Absorption spectroscopy
Organic Chemistry Substituent Carbon-13 NMR Conjugated system Biochemistry Phosphonate Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Ferrocene Heck reaction Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Cyclic voltammetry |
| Zdroj: | Journal of Organometallic Chemistry. 689:1867-1871 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2004.03.007 |
| Popis: | The synthesis of para -substituted ferrocene analogues of stilbene was performed by using the Heck reaction, starting from vinylferrocene. The variation of the electronic density of these compounds with the electronic withdrawing strength of the substituents was studied using 13 C NMR spectroscopy, absorption spectra and cyclic voltammetry. The correlation of Hammett constants with the redox properties of the substituted compounds using Nagy's method allowed us to revisit the determination of the Hammett constants of diethyl phosphonate ester and phosphonic acid substituents. Our measurements were in agreement with the literature except for the diethyl phosphonate group. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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