Gold- and Silver-Catalysed Cyclisation Reactions of β-Amino Allenes

Autor:	Anthony C. Willis, Christopher J. T. Hyland, Stephen G. Pyne, Liam M. Joyce
Rok vydání:	2018
Předmět:	Green chemistry Reaction mechanism 010405 organic chemistry Allene Supramolecular chemistry General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Biocatalysis Yield (chemistry) Ionic liquid
Zdroj:	Australian Journal of Chemistry. 71:682
ISSN:	0004-9425
DOI:	10.1071/ch18197
Popis:	Herein we report the formation of pyrrolines and tetrahydropyridines from the cyclisation reactions of β-amino allenes by both AuI and AgI catalysts in yields ranging from 5 to 70 %. AuI catalysts favour a 5-endo-dig cyclisation before rapid rearrangement to the 5-exo-dig product, while AgI favours a 6-endo-trig cyclisation. We also report the first known Ag2O catalysed cyclisation reaction of an allene which occurred in good yield (61 %).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d0d350ba4066e426747844dc8d6de55 https://doi.org/10.1071/ch18197 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.