The reactions of RuCl3(NO)(PPh3)2 and RuCl3(NO)·H2O with Ph2P(CH2) P(O)Ph2, n = 1, 2, or 3: Crystal structures of ruthenium nitrosyl complexes containing monodentate and chelating Ph2P(CH2) P(O)Ph2 ligands

Autor:	Sadie E. Knight, Donna S. Amenta, John W. Gilje, Samantha K. Herold, Glenn P. A. Yap, Katherine J. Olsonowski, Lindsay R. Walton
Rok vydání:	2018
Předmět:	Denticity Ligand chemistry.chemical_element Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Ruthenium Inorganic Chemistry chemistry Materials Chemistry Chelation Physical and Theoretical Chemistry
Zdroj:	Polyhedron. 144:44-54
ISSN:	0277-5387
Popis:	The reaction of RuCl3(NO)(PPh3)2 or RuCl3(NO)·H2O with Ph2P(CH2)nP(O)Ph2 (n = 1, 2, or 3) yields trans-RuCl3(NO)[Ph2P(CH2)nP(O)Ph2]2. Depending on conditions {RuCl2(NO)[Ph2PCH2P(O)Ph2]2}Cl, which contains one chelating and one monodentate ligand, can also be obtained. Reactions of RuCl3(NO)[Ph2PCH2P(O)Ph2]2 with AgBF4 form {RuCl2(NO)[Ph2PCH2P(O)Ph2]2}BF4, which contains the same cation as {RuCl2(NO)[Ph2PCH2P(O)Ph2]2}Cl, and RuCl(NO)[Ph2PCH2P(O)Ph2]2}(BF4)2, in which both ligands chelate. The reaction of RuCl3(NO)[Ph2P(CH2)2P(O)Ph2]2 with AgBF4 has led to {RuCl2(NO)[Ph2P(CH2)2P(O)Ph2]2}(BF4), where one ligand chelates and the second is monodentate, and to{RuCl2[Ph2P(CH2)2P(O)Ph2]2}(BF4)2, a Ru(III) complex that no longer contains an nitrosyl ligand. With the exception of trans-RuCl3(NO)[Ph2P(CH2)3P(O)Ph2]2 and {RuCl2(NO)[Ph2PCH2P(O)Ph2]2}(BF4) crystal structures of these compounds have be obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d0b00f490c277be829a7d7cacac19c5 https://doi.org/10.1016/j.poly.2018.01.001 Zobrazit plný text záznamu Full Text from ScienceDirect