Kinetics and mechanism of the chromic oxidation of myo-inositol

Autor:	Mabel Santoro, László Korecz, Evangelina Caffaratti, Antal Rockenbauer, Juan M. Salas-Peregrín, Sandra Signorella, Luis F. Sala
Rok vydání:	2007
Předmět:	Chromate conversion coating Cyclitol Kinetics Inorganic chemistry Medicinal chemistry Redox law.invention Inorganic Chemistry chemistry.chemical_compound chemistry law Materials Chemistry Inositol Physical and Theoretical Chemistry Electron paramagnetic resonance
Zdroj:	Polyhedron. 26:169-177
ISSN:	0277-5387
DOI:	10.1016/j.poly.2006.08.003
Popis:	The oxidation of d -myo-inositol (Myo) by CrVI yields the inosose and Cr3+ as final products when an excess of cyclitol over CrVI is used. The redox reaction takes place through the combination of CrVI → CrIV → CrII and CrVI → CrIV → CrIII pathways. Intermediacy of CrIV was evidenced by the detection of CrO 2 2 + , formed by reaction of CrII with O2. The EPR spectra show that five- and six-coordinated oxo-CrV intermediates are formed, with the cyclitol acting as bidentate ligand. Penta-coordinated oxo-CrV species are present at any [H+], whereas hexa-coordinated ones are only observed at pH
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5d0957de4b813425509893a629446419 https://doi.org/10.1016/j.poly.2006.08.003 Zobrazit plný text záznamu Full Text from ScienceDirect